Nucleophilic Elimination‐Cycloaddition of α,ω‐Alkanediyl Bis(triflates), a Novel Method for the Synthesis of Metallacycles with Reactive Metal‐Carbon σ Bonds | Zendy

Lindner Ekkehard | Zendy; Eberle HansJürgen | Zendy

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Nucleophilic Elimination‐Cycloaddition of α,ω‐Alkanediyl Bis(triflates), a Novel Method for the Synthesis of Metallacycles with Reactive Metal‐Carbon σ Bonds

Author(s) -

Lindner Ekkehard,

Eberle HansJürgen

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198000731

Subject(s) - nucleophile , catalysis , manganese , cycloaddition , chemistry , medicinal chemistry , metal , carbon fibers , reactive intermediate , combinatorial chemistry , organic chemistry , materials science , composite number , composite material

Stable heterocycles (1) with MnC σ‐bond —of significance for catalytic reactions—have been synthesized by reaction of manganese‐containing dianions and alkylenebis(triflates) (ZOSO 2 CF 3 ). Insertion of CO into the M—C bond of a metallacycloalkane has now be accomplished for the first time with (1) , XCH 2 CH 2 .

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