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Nucleophilic Elimination‐Cycloaddition of α,ω‐Alkanediyl Bis(triflates), a Novel Method for the Synthesis of Metallacycles with Reactive Metal‐Carbon σ Bonds
Author(s) -
Lindner Ekkehard,
Eberle HansJürgen
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198000731
Subject(s) - nucleophile , catalysis , manganese , cycloaddition , chemistry , medicinal chemistry , metal , carbon fibers , reactive intermediate , combinatorial chemistry , organic chemistry , materials science , composite number , composite material
Stable heterocycles (1) with MnC σ‐bond —of significance for catalytic reactions—have been synthesized by reaction of manganese‐containing dianions and alkylenebis(triflates) (ZOSO 2 CF 3 ). Insertion of CO into the M—C bond of a metallacycloalkane has now be accomplished for the first time with (1) , XCH 2 CH 2 .