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Synthesis and Reactions of Diorganophosphinite Complexes of Gold
Author(s) -
Schmidbaur Hubert,
Aly M. A. Aref A. M.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198000711
Subject(s) - phosphinite , oxygen atom , ion , chemistry , salt (chemistry) , moisture , atom (system on chip) , oxygen , atmospheric oxygen , molecule , organic chemistry , catalysis , computer science , embedded system
The donor properties of the phosphorus atom are only slightly poorer in phosphinite ions [R 2 PO] − than in phosphanes R 3 P; the oxygen atom can also be coordinated. The phosphane‐gold (1) phosphinite (1) 2 which is stable to air, moisture, and heating up to 350°C, and the salt‐like compounds (2) , RMe, Ph, represent new examples of this type.