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μ‐Alkylthio‐ and μ‐Arylthio‐μ‐chlorodicarbonylbis (tri‐ tert ‐butylphosphane)dirhodium: Dinuclear Rhodium Complexes with Different Bridging Ligands
Author(s) -
Schumann Herbert,
Cielusek Guy,
Pickardt Joachim
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198000701
Subject(s) - rhodium , bridging (networking) , chemistry , crystal structure , stereochemistry , bridge (graph theory) , catalysis , crystallography , organic chemistry , computer science , computer network , medicine
Hydrogenations, decarboxylations, and isomerizations are catalyzed by the dirhodium complexes of type (3) , the first stable compounds having a Cl and an SR bridge. The structure of (3) , R= t Bu, has been elucidated by crystal structure analysis.