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Synthesis and Properties of the First Organosilyl‐Gallium Compounds
Author(s) -
Rösch Lutz,
Neumann Heinrich
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198000551
Subject(s) - gallium , tetrahydrofuran , sublimation (psychology) , adduct , chemistry , solvent , indium , derivative (finance) , silylation , tris , organic chemistry , psychology , biochemistry , financial economics , economics , psychotherapist , catalysis
Tris(trimethyl)silyl compounds of all GroupIIIB metals are known now that the synthesis of Ga(SiMe 3 ) 3 has been accomplished. The tetrahydrofuran adduct (1) initially obtained can be freed from solvent by sublimation in a high vacuum. Ga(SiMe 3 ) 3 resembles the indium derivative more closely than the (associating) aluminum derivative.