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Preparation of 1‐ tert ‐Butyl‐3‐methyl‐2‐phenyl‐Δ 3 ‐1,2‐azaboroline and Utilization of Its Anion as a Complex Ligand Analogous to Cyclopentadienyl
Author(s) -
Schulze Joachim,
Schmid Günter
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198000541
Subject(s) - cyclopentadienyl complex , ligand (biochemistry) , chemistry , derivative (finance) , metal , medicinal chemistry , ion , stereochemistry , organic chemistry , catalysis , receptor , biochemistry , financial economics , economics
Relatives of the “everyday” ligand cyclopentadienyl , such as the Δ 3 ‐1,2‐azaboroline derivative (1) , should permit preparation of numerous metal complexes. Complex (2) , the first one to contain the anion of (1) , resembles its cyclopentadienyl analog very closely.