Structural Investigations on (η 12 ‐[3.3]Paracyclophane)chromium( 0 ) and Its Cation in (η 12 ‐[3.3]Paracyclophane)chromium( I ) Triiodide | Zendy

Benn Reinhard | Zendy; Blank Norman E. | Zendy; Haenel Matthias W. | Zendy; Klein Jochen | Zendy; Koray Ali R. | Zendy; Weidenhammer Klaus | Zendy; Ziegler Manfred L. | Zendy

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Structural Investigations on (η 12 ‐[3.3]Paracyclophane)chromium( 0 ) and Its Cation in (η 12 ‐[3.3]Paracyclophane)chromium( I ) Triiodide

Author(s) -

Benn Reinhard,

Blank Norman E.,

Haenel Matthias W.,

Klein Jochen,

Koray Ali R.,

Weidenhammer Klaus,

Ziegler Manfred L.

Publication year - 1980

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198000441

Subject(s) - chromium , cyclophane , triiodide , chemistry , crystal structure , crystallography , salt (chemistry) , stereochemistry , organic chemistry , electrode , dye sensitized solar cell , electrolyte

The first crystal structure analysis of a chromium insertion product in a cyclophane has been achieved on the salt (1) , whose cation exists exclusively in the chair conformation. In contrast, according to its 1 H‐NMR spectrum, the corresponding chromium(0) compound is present in the boat conformation (2) and the chair conformation (3) in a ratio of 1:1 in solution at −70°C.

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