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A Model of Hydrogen‐Bonded Liquids
Author(s) -
Luck Werner A. P.
Publication year - 1980
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198000281
Subject(s) - simple (philosophy) , hydrogen bond , orientation (vector space) , liquid water , materials science , statistical physics , computational chemistry , chemical physics , thermodynamics , chemistry , molecule , physics , mathematics , organic chemistry , geometry , philosophy , epistemology
The orientation defect model can be used for quantitative estimates and for understanding the properties of H‐bonded liquids, such as water and alcohol. The defect concentrations can be determined by vibrational spectroscopy, and the applicability of the approximation procedure derives from considering H‐bonds as chemical equilibria. Possible extensions of the simple model are critically discussed.