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One‐Pot Syntheses of α‐Ferrocenylalkylamines
Author(s) -
Herrmann Rudolf,
Ugi Ivar
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197909561
Subject(s) - trichloroacetic acid , ferrocene , amine gas treating , chemistry , combinatorial chemistry , solvent , peptide , organic chemistry , biochemistry , electrochemistry , electrode
In order to carry out asymmetric peptide syntheses with 1‐ferrocenyl‐2‐methylpropylamine on a large scale a convenient entry to this amine and similar compounds has been developed. One‐pot syntheses in the trichloroacetic acid/fluorosulfuric acid solvent proved favorable(FcH = ferrocene).