The Homologous Series of Cyclic Polysilanes from (Me 2 Si) 5  to (Me 2 Si) 35 | Zendy

Brough Lawrence F. | Zendy; Matsumura Koichi | Zendy; West Robert | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The Homologous Series of Cyclic Polysilanes from (Me 2 Si) 5 to (Me 2 Si) 35

Author(s) -

Brough Lawrence F.,

Matsumura Koichi,

West Robert

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197909551

Subject(s) - homologous series , tetrahydrofuran , boiling , sublimation (psychology) , recrystallization (geology) , alloy , materials science , boiling point , crystallography , chemistry , analytical chemistry (journal) , organic chemistry , psychology , paleontology , solvent , psychotherapist , biology

Permethylsilicon rings having 5 through 35 members arise on slow addition of Me 2 SiCl 2 to Na/K alloy in boiling tetrahydrofuran. After removal of the major products (Me 2 Si) 5 and (Me 2 Si) 6 (recrystallization and fractional sublimation) the cyclic polysilanes can be detected by high pressure liquid chromatography.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research