Ion Cyclotron Resonance Studies on  tert ‐Butyl, 2‐Norbornyl, and 1‐ and 2‐Adamantyl Cations | Zendy

Houriet Raymond | Zendy; Schwarz Helmut | Zendy

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Ion Cyclotron Resonance Studies on tert ‐Butyl, 2‐Norbornyl, and 1‐ and 2‐Adamantyl Cations

Author(s) -

Houriet Raymond,

Schwarz Helmut

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197909511

Subject(s) - 2 norbornyl cation , chemistry , ion , medicinal chemistry , ion cyclotron resonance , computational chemistry , stereochemistry , cyclotron , organic chemistry

The discussion about “classical”/“nonclassical”cations continues. ICR studies show that the 1‐adamantyl cation is certainly not exceptionally stabilized (as has been repeatedly suspected) and that the energy of the 2‐adamantyl cation differs by only 4 kcal/mol instead the expected amount of 16 kcal/mol. The analogy with the controversial 2‐norbornyl cation/2‐methyl‐2‐norbornyl cation system cannot be overlooked.

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