New Pathways to Trinuclear Complexes—Structure of the Tetra‐decker Sandwich Complex Bis(η‐thiadiborolenecobalt‐μ,η‐thiadiborolene)iron | Zendy

Siebert Walter | Zendy; Rothermel Wilfried | Zendy; Böhle Christian | Zendy; Krüger Carl | Zendy; Brauer David J. | Zendy

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New Pathways to Trinuclear Complexes—Structure of the Tetra‐decker Sandwich Complex Bis(η‐thiadiborolenecobalt‐μ,η‐thiadiborolene)iron

Author(s) -

Siebert Walter,

Rothermel Wilfried,

Böhle Christian,

Krüger Carl,

Brauer David J.

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197909491

Subject(s) - tetra , chemistry , crystallography , yield (engineering) , cleavage (geology) , stereochemistry , medicinal chemistry , materials science , metallurgy , composite material , fracture (geology)

Cleavage of triple‐decker compounds with cyclopentadienide leads to anionic mononuclear complexes, which react to form trinuclear complexes. Thus the hitherto relatively inaccessible compound [ (1) ·Co· (1) ·Fe· (1) ·Co· (1) ] has been obtained in 29% yield from [ (1) ·Co· (1) ·Co· (1) ] via [ (1) ·Co· (1) ] ⊖ . X‐ray structure analysis confirmed the proposed tetra‐decker geometry.

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