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Dithiiranes and Thiosulfines as Reactive Intermediates
Author(s) -
Senning Alexander
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197909411
Subject(s) - morpholine , reactive intermediate , chemistry , ring (chemistry) , medicinal chemistry , stereochemistry , organic chemistry , catalysis
The intermediacy of theCSS ring and/or itsisomer appears likely from new experiments: reaction of (1) with morpholine leads via the unstable α‐chloroalkyldisulfanes and the dithio esters (4) to stable products. (2)/(3) has not yet been trapped (R 1 ,R 2 CI; R 1 PhS, R 2 Tos).