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Enantioselective Oxidation by a Chiral Acylaminyl Oxide
Author(s) -
Berti Corrado,
Perkins M. John
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197908641
Subject(s) - benzil , enantioselective synthesis , oxidizing agent , enantiomer , reactivity (psychology) , chemistry , oxide , combinatorial chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology
A new oxidizing agent having remarkable properties has been found in the readily accessible chiral radical (1) . It preferentially oxidizes one enantiomer of the test substances D , L ‐benzil and D , L ‐benzion, so thet the other enentiomer accumulates. The reactivity and enantioselectivity of (1) should be enhanced by other substituents.
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