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Synthesis and X‐Ray Structure Analysis of a Mo Complex with η 2 ‐Coordinated Benzaldehyde; Transformation of a CO Ligand by Double α‐Addition
Author(s) -
Brunner Henri,
Wachter Joachim,
Bernal Ivan,
Creswick Michael
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197908611
Subject(s) - benzaldehyde , molar ratio , chemistry , molybdenum , ligand (biochemistry) , x ray , crystallography , stereochemistry , atom (system on chip) , medicinal chemistry , inorganic chemistry , organic chemistry , computer science , physics , receptor , catalysis , parallel computing , optics , biochemistry
Molybdenum serves as spiro‐atom in the complex (3) formed from (1) , R CH 3 , and PhMgBr in the molar ratio of 1:2. One of the two CO groups is transformed into C,O ‐coordinated benzaldehyde. Ring contraction (1) → (2) is already known.