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Synthesis and Crystal Structure of a Chiral Complex Containing a Non‐linear Heterotrimetal Chain: PtMn 2 (μ 2 ‐PPh 2 ) 2 (CO) 9
Author(s) -
Braunstein Pierre,
Matt Dominique,
Bars Odile,
Grandjean Daniel
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197907972
Subject(s) - chain (unit) , crystal structure , crystallography , stereochemistry , materials science , chemistry , physics , quantum mechanics
Complexes containing chains of three metal atoms are still rare species. (2) is the first neutral compound having a non‐linear M 1 M 2 M 1 chain and is also chiral (X‐ray structure analysis).