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A 3‐Imino‐1,2‐dioxetane via Singlet Oxygenation of a Ketenimine
Author(s) -
Adam Waldemar,
De Lucchi Ottorino,
Quast Helmut,
Reckterwald Rautgundis,
Yany Faris
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197907881
Subject(s) - ketenimine , homolysis , photochemistry , dioxetane , singlet state , chemistry , singlet oxygen , radical , stereochemistry , oxygen , atomic physics , organic chemistry , chemiluminescence , physics , excited state
In connection with “photochemistry without light” (or chemi‐energized electronic excitation) interest attaches to the 3‐imino‐1,2‐dioxetane (1) , which has been synthesized as the first representative of its class. Compound (1) , is stable at low tempertature. Homolysis of the OO bond to form the elusive 1,4‐dioxyl radical in heating could not be detected.