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Preparation and Chemiluminescence of cis ‐1,2‐Cyclobutylene Dinitrite
Author(s) -
Suzuki Nobutaka
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197907872
Subject(s) - chemiluminescence , diradical , photochemistry , chemistry , light emission , hydrolysis , materials science , organic chemistry , physics , atomic physics , optoelectronics , singlet state , excited state
The chemiluminescence of 1,2‐dioxetanes (1) has been examined with the aid of the title compound (2) , RR = (CH 2 ) 2 This hydrolysis‐sensitve model compound exhibits very weak emission of light on heating in the presence of dibromoanthracene, which could arise from the diradical (3) . It is deduced that 1,2‐dioxetanes (1) decompose mainly in a concerted manner.
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