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Chemistry of the H 3 B(CH 3 ) 2 P Group : Unusual Properties of Some Simple Reference Compounds
Author(s) -
Schmidbaur Hubert,
Weiss Erwin
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197907811
Subject(s) - simple (philosophy) , disiloxane , chemistry , group (periodic table) , analogy , moisture , organic chemistry , philosophy , epistemology , catalysis , linguistics
The analogy between the isoelectronic groups Me 3 Si and Me 2 (H 3 B)P exists not only on paper. For example, the Me 3 SiCl analogue (1) is stable, distillable and relatively insensitive to moisture; on treatment with Ag 2 O it affords the air‐ and water‐stable compound (2) corresponding to disiloxane.