Crystal Structure of Na 3 NO 4 | Zendy

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Crystal Structure of Na 3 NO 4

Author(s) -

Jansen Martin

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197906982

Subject(s) - crystallography , tetrahedron , bond length , group (periodic table) , crystal structure , bond , chemistry , polar , crystal (programming language) , materials science , physics , computer science , organic chemistry , finance , astronomy , programming language , economics

NO 4 3−is the “smallest” tetrahedral oxoanion so far , as shown by X‐ray structure analysis of painstakingly group (240 d) single crystals of Na 3 NO 4 . The NO distances (139 pm) are shorter than expected ( ca. 150 pm); the shortening can only be due to polar interactions superimposed on the single bond. In this way, the bond lengths in PO 4 3− , SO 4 2− , or ClO 4 −could also be explained without invoking pd‐π bonding.

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