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Synthesis of Allenes from Electrophilic Acetylenes via Novel Allenemanganese Complexes
Author(s) -
FranckNeumann Michel,
Brion Francis
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197906881
Subject(s) - electrophile , chemistry , allene , combinatorial chemistry , stereochemistry , organic chemistry , catalysis
The isomerization of readily accessible acetylenes to allenes can be accomplished as shown below. Surprisingly, allenes are stabilized by Mn complexes (MnL 3 (CH 3 C 5 H 4 )Mn(CO) 2 ).