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Metal Complexes of Bredt Olefins: Synthesis and Structure of Bicyclo[4.2.1]non‐1(8)‐enebis(triphenylphosphane)platinum(0)
Author(s) -
Stamm Erich,
Becker Konrad B.,
Engel Peter,
Ermer Otto,
Keese Reinhart
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197906851
Subject(s) - olefin fiber , platinum , metal , chemistry , bicyclic molecule , stereochemistry , crystallography , computational chemistry , organic chemistry , catalysis
Reversible stabilization of a Bredt olefin has been accomplished for the first time with a platinum(0) compound. In complex (3) (X‐ray structure analysis) the olefin has the same conformation as free (2) (force field calculations). Treatment of the complex with CS 2 regenerates isomer‐free (2) .
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