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An ortho ‐Palladated Complex of 2,5‐Diphenyl‐1,6,6aλ 4 ‐trithiapentalene
Author(s) -
Bogdanović Borislav,
Krüger Carl,
Locatelli Paolo
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197906841
Subject(s) - metal , chemistry , organic chemistry
Syntheses of complexes having several different metal atoms are possible with (1) , which is obtained by ortho ‐palladation of trithiapentalene. (1) undergoes quantitative reaction with, e. g. , MoCl 5 to give [ (1) ·MoCl 3 ] x , which has yet to be characterized in detail.