Complexes of Nitrogen‐Containing Crown Ether Surfactants with Stable Silver Atoms | Zendy

HumphryBaker Robin | Zendy; Grätzel Michael | Zendy; Tundo Pietro | Zendy; Pelizzetti Ezio | Zendy

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Complexes of Nitrogen‐Containing Crown Ether Surfactants with Stable Silver Atoms

Author(s) -

HumphryBaker Robin,

Grätzel Michael,

Tundo Pietro,

Pelizzetti Ezio

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197906301

Subject(s) - cyanine , crown ether , pulmonary surfactant , ether , chemistry , photochemistry , ion , nitrogen , polymer chemistry , inorganic chemistry , organic chemistry , biochemistry , physics , quantum mechanics , fluorescence

Photochemical reduction of complexed Ag + ions to stable complexed Ag atoms can be accomplished with the aid of the heterocycle (1) , which combines the properties of a crown ether and of a surfactant. (1) Ag + is formed spontaneously from (1) and AgNO 3 ; reduction with visible light requires a cyanine dye as sensitizer.

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