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[{Cu 3 WS 3 Cl}(PPh 3 ) 3 O], Directed Synthesis of a Compound Containing Different Metal Atoms in a Cu‐bane‐like Skeleton
Author(s) -
Müller Achim,
Hwang Theng Khing,
Bögge Hartmut
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197906281
Subject(s) - synthon , cubane , copper , chemistry , crystallography , metal , crystal structure , stereochemistry , organic chemistry
A “synthon” suitable for a copper‐ and sulfurcontaining compound with a cubane skeleton is the “ready‐made corner” OWS 3 2− . Reaction of Cs 2 WOS 3 with CuCL 2 and PPh 3 expectedly (preferred formation of CuS as aginst CuO bonds) gives comples (1) . Cu‐bane‐type structure containing Cu and S were formerly unknown.