Synthesis and Intramolecular 1,3 Cl,H Disproportionation of Ethyl 2,2‐Dichloro‐2‐(dimethylamino)‐acetate | Zendy

Huys Fabienne | Zendy; Merényi Robert | Zendy; Janousek Zdenek | Zendy; Stella Lucien | Zendy; Viehe Heinz Günter | Zendy

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Synthesis and Intramolecular 1,3 Cl,H Disproportionation of Ethyl 2,2‐Dichloro‐2‐(dimethylamino)‐acetate

Author(s) -

Huys Fabienne,

Merényi Robert,

Janousek Zdenek,

Stella Lucien,

Viehe Heinz Günter

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197906151

Subject(s) - disproportionation , intramolecular force , geminal , chemistry , radical disproportionation , radical , derivative (finance) , acceptor , medicinal chemistry , substitution (logic) , photochemistry , stereochemistry , organic chemistry , catalysis , physics , computer science , financial economics , economics , programming language , condensed matter physics

Compounds having geminal capto‐dative substitutents contain a donor and an acceptor group bonded to the same C atom;such substitution stabilizes radicals. Compound (1) is an example; its remarkable Cl,H disproportionation to give the glyoxalic ester derivative (2) probably proceeds via a radical.

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