Hexamethyldisilane/Iodine: Convenient  In Situ  Generation of Iodotrimethylsilane | Zendy

Olah George A. | Zendy; Narang Subhash C. | Zendy; Gupta B. G. Balaram | Zendy; Malhotra Ripudaman | Zendy

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Hexamethyldisilane/Iodine: Convenient In Situ Generation of Iodotrimethylsilane

Author(s) -

Olah George A.,

Narang Subhash C.,

Gupta B. G. Balaram,

Malhotra Ripudaman

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197906121

Subject(s) - reagent , in situ , chemistry , iodine , combinatorial chemistry , cleavage (geology) , organic chemistry , chromatography , geology , geotechnical engineering , fracture (geology)

Organic syntheses involving iodotrimethylsilane , e.g. cleavage of esters, ethers, snd carbamates under mild conditions, have advantages but Me 3 SiI is not readily obtainable and is also a sensitive compound. These difficulties are overcome by the Me 3 SiSiMe 3 /I 2 reagent which can be used for convenient in‐situ generation of Me 3 SiI.

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