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Hexamethyldisilane/Iodine: Convenient In Situ Generation of Iodotrimethylsilane
Author(s) -
Olah George A.,
Narang Subhash C.,
Gupta B. G. Balaram,
Malhotra Ripudaman
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197906121
Subject(s) - reagent , in situ , chemistry , iodine , combinatorial chemistry , cleavage (geology) , organic chemistry , chromatography , geology , geotechnical engineering , fracture (geology)
Organic syntheses involving iodotrimethylsilane , e.g. cleavage of esters, ethers, snd carbamates under mild conditions, have advantages but Me 3 SiI is not readily obtainable and is also a sensitive compound. These difficulties are overcome by the Me 3 SiSiMe 3 /I 2 reagent which can be used for convenient in‐situ generation of Me 3 SiI.