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Synthesis of a Hydroxylamido(2−)‐ O,N ‐(nitrosyl)molybdenum Complex
Author(s) -
Wieghardt Karl,
Holzbach Wolfgang
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197905491
Subject(s) - hydroxylamine , denticity , cyanide , molybdenum , perchlorate , chemistry , ligand (biochemistry) , terpyridine , medicinal chemistry , stereochemistry , inorganic chemistry , ion , crystallography , organic chemistry , crystal structure , metal , receptor , biochemistry
The first complex to contain the bidentate ligand [H N O] 2− has been isolated and characterized. Mo VI oxo anions react with hydroxylamine and terpyridine (tpy)to give a yellow cation (1) which can be isolated as the perchlorate. The red neutral complex (2) is formed reversibly from (1) and cyanide.