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Reactions of Molybdate( VI ) with Hydroxylamine and N ‐Methylhydroxylamine
Author(s) -
Wieghardt Karl,
Holzbach Wolfgang,
Weiss Johannes,
Nuber Bernhard,
Prikner Boris
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197905481
Subject(s) - hydroxylamine , molybdenum , molybdate , aqueous solution , chemistry , inorganic chemistry , sodium molybdate , medicinal chemistry , nuclear chemistry , organic chemistry
Two remarkable molybdenum complexes have been isolated on recation of aqueous solutions of Mo VI oxo anions with H 2 NOH or MeHNOH: the yellow NO complex (1) and the colorless NO‐free neutral complex (2) . This shows that many yellow Mo complexes characterized only in solution pribably contain NO ligands.

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