Premium
Heptalenebis(tricarbonyliron)
Author(s) -
Vogel Emanuel,
Kerimis Dimitrios,
Allison Neil T.,
Zellerhoff Robert,
Wassen Jürgen
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197905451
Subject(s) - chemistry , derivative (finance) , stereochemistry , double bond , combinatorial chemistry , medicinal chemistry , organic chemistry , economics , financial economics
The synthesis of substituted heptalenes , e.g (3) and (4) , can be accomplished via the bis(tricarbonyliron) derivative (2) formed from (1) and benzylideneacetone(tricarbonyliron). This entry into the chemistry of substituted heptalenes is facilitated by a new heptalene synthesis involving protection of the central double bond of isotetralin by epoxidation.