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Manganese‐Containing Heterocycles Having a λ 4 ‐Thia‐λ 5 ‐phosphanorbornadiene Skeleton
Author(s) -
Lindner Ekkehard,
Rau Axel,
Hoehne Sigurd
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197905341
Subject(s) - manganese , acetylene , catalysis , chemistry , skeleton (computer programming) , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry , computer science , programming language
A new pathway leading to metallacycles of type (2) consists in the reaction of inorganic heterocycles such as (1) with acetylene derivatives. Compounds (2) (R 1 Me, Ph;R 2 CO 2 Me, CO 2 Et) have been characterized by X‐ray structure analysis. Such heterocycles are of importance in organic synthesis, especially in catalytic processes.