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A New Lithium‐Nickel Polynuclear Complex: Ni(C 12 H 17 NiLi) 2 (THF) 4
Author(s) -
Jonas Klaus,
Krüger Carl,
Sekutowski Janine C.
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904871
Subject(s) - nickel , yield (engineering) , lithium (medication) , chemistry , nickel compounds , crystallography , materials science , metallurgy , organic chemistry , medicine , endocrinology
Three linearly arranged nickel atoms and two coordinatively unsaturated Li and two pentacoordinated C atoms present in the new complex (2) (C 12 H 18 = all‐cis ‐1,5,9‐cyclododecatriene). Compound (2) , formed as by‐product in the lithiation of C 11 H 18 Ni 0 , was obtained from (1) in 30% yield.