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Krypton and Xenon Inclusion Compounds of Complex Metal Cyanides
Author(s) -
Kämper Manfred,
Wagner Madlon,
Weiss Armin
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904861
Subject(s) - krypton , xenon , bar (unit) , inclusion (mineral) , crystallization , noble gas , metal , crystallography , chemistry , materials science , inorganic chemistry , metallurgy , mineralogy , physics , organic chemistry , meteorology
The inclusion of noble gases in host lattices — e.g. CdPt(CN) 6 takes up 1.046 Kr or 1.128 Xe per formula unit if the crystals are grown in the presence of the gas (64 bar)—corresponds to a compression (⩾118 bar). However, CdPt(CN) 6 is too expensive for industrial use. The cavities of the cage structure surprisingly remain vacant on crystallization from water.