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Stepwise Reaction of Phenylbis(trimethylsilyl)phosphane with Phosgene—Isolation of a (Phosphinomethylene)phosphane
Author(s) -
Appel Rolf,
Barth Volker
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904692
Subject(s) - phosgene , trimethylsilyl , chemistry , isolation (microbiology) , medicinal chemistry , organic chemistry , bioinformatics , biology
Three intermediates of chlorination of PhP(SiMe 3 ) 2 with phosgene have been isolated and some of them characterized. The open‐chain compound (2) having a PC bond deserves special mention.