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tetrahedro ‐Tetraphosphorus as Monodentate Ligand in a Nickel(0) Complex
Author(s) -
Dapporto Paolo,
Midollini Stefano,
Sacconi Luigi
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904691
Subject(s) - ligand (biochemistry) , nickel , denticity , chemistry , phosphorus , crystallography , molecule , atom (system on chip) , crystal structure , organic chemistry , biochemistry , computer science , receptor , embedded system
An intact P 4 molecule is coordinated as η 1 ligand to Ni 0 in complex (2) . X‐ray structure analysis reveals that the nickel atom is in an approximately tetrahedral environment of three phosphorus atoms of the additional ligand “np 3 ” and one phosphorus atom of the P 4 unit.