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Catalysis of Hydrogen Formation from an Organic Radical in Aqueous Solutions by Colloidal Silver
Author(s) -
Henglein Arnim
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904181
Subject(s) - radical , aqueous solution , colloid , catalysis , redox , chemistry , photochemistry , inorganic chemistry , organic chemistry
Short‐lived radicals such as (1) can be compelled to undergo unusual reactions if they are generated in the presence of a metal colloid catalyst in aqueous solution. Instead of combining, disprotionating, or dismuting, the radicals (1) participate in a redox process leading to evolution of H 2 , according to the overall equation:
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