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Structural Isomers of Palladium Complexes of Type C 5 H 5 Pd(2‐RC 3 H 4 )L — A Case of Simultaneous π/σ and σ/π Rearrangement of Two Organic Ligands
Author(s) -
Werner Helmut,
Kühn Alfred
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904161
Subject(s) - palladium , chemistry , stereochemistry , structural isomer , crystallography , catalysis , organic chemistry
Interesting structural features of palladium complexes have been observed for (1) : in solution (1a) undergoes very fast metallotropic rearrangement, i.e. it has a fluxional structure, whereas two bond isomers interconvert in the case of the homologous compound (1b) .
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