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syn ‐Anthracene 4a,10:9,9a‐Dioxide
Author(s) -
Rigaudy Jean,
Defoin Albert,
BaranneLafont Joële
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197904131
Subject(s) - isomerization , anthracene , epoxide , chemistry , photochemistry , thermolabile , medicinal chemistry , irradiation , organic chemistry , catalysis , physics , nuclear physics , enzyme
The rearrangement of an epidioxide to a compound with two epoxide groups known to occur with cycloalkienes and substituted arenes–has now accomplished with unsubstituted (1) by prolonged irradiation (λ > 435 nm). (2) is the thermolabile primary product of thermal isomerization of (1) .