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Carbene‐Carbene Rearragements of cis ‐and trans ‐2‐(1,3‐Butadienyl)cyclopropylidene
Author(s) -
Brinker Udo H.,
Fleischhauer Ilona
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197903961
Subject(s) - carbene , chemistry , stereochemistry , catalysis , organic chemistry
The configurationally isomeric carbenes (1) and (2) –the first such pair obtained–behave with remarkable regiospecificity in carbene‐carbene rearrangements. The 1,5‐C shifts (2) → (3) is new.
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