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Oxidative Addition to a Quadruple Bond. The Complete X‐ray Structure of [Mo 2 Cl 8 H] 3−
Author(s) -
Bino Avi,
Cotton F. Albert
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197903321
Subject(s) - molybdenum , crystallography , ion , oxidative addition , hydride , chemistry , x ray , atom (system on chip) , x ray crystallography , bond length , crystal structure , stereochemistry , physics , inorganic chemistry , diffraction , metal , nuclear physics , organic chemistry , optics , computer science , embedded system , catalysis
Oxidatve addition to an MM bond has now been demonstrated for the molybdenum compound (1) by X‐ray structure analysis of the anion (2) . The species (2) contains a symmetrically bridging H atom with appreciable hydride character.