Oxidative Addition to a Quadruple Bond. The Complete X‐ray Structure of [Mo 2 Cl 8 H] 3− | Zendy

Bino Avi | Zendy; Cotton F. Albert | Zendy

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Oxidative Addition to a Quadruple Bond. The Complete X‐ray Structure of [Mo 2 Cl 8 H] 3−

Author(s) -

Bino Avi,

Cotton F. Albert

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197903321

Subject(s) - molybdenum , crystallography , ion , oxidative addition , hydride , chemistry , x ray , atom (system on chip) , x ray crystallography , bond length , crystal structure , stereochemistry , physics , inorganic chemistry , diffraction , metal , nuclear physics , organic chemistry , optics , computer science , embedded system , catalysis

Oxidatve addition to an MM bond has now been demonstrated for the molybdenum compound (1) by X‐ray structure analysis of the anion (2) . The species (2) contains a symmetrically bridging H atom with appreciable hydride character. 

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