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Photochemical Behavior of N 2 ‐Complexes: Photoluminescence of trans ‐(N 2 ) 2 W(diphos) 2 and trans ‐(CO) 2 W(diphos) 2
Author(s) -
Caruana Albert,
Kisch Horst
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197903281
Subject(s) - photoluminescence , transition metal , chemistry , visible spectrum , metal , photochemistry , materials science , crystallography , catalysis , optoelectronics , biochemistry , organic chemistry
The first photoluminescing dinitrogen complex trans ‐(N 2 ) 2 W(diphos) 2 (1) is also the first transition‐metal(o) compound to show a structured emission spectrum. These finding are of considerable significance for the photochemical reduction of complexed N 2 .
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