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Complex‐Stabilized Hydroxy ( p ‐tolyl)acetylene by Reaction of trans ‐Chlorotetracarbonyl(tolylcarbyne)tungsten with Acetylacetone
Author(s) -
Fischer Ernst Otto,
Friedrich Peter
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197903271
Subject(s) - acetylacetone , acetylene , carbyne , chemistry , tungsten , crystal structure , atom (system on chip) , photochemistry , transition metal , crystallography , carbene , catalysis , inorganic chemistry , organic chemistry , computer science , embedded system
An “acetylene alcohol” , which is stabilized by coordination to a transition metal to atom, arises on photochemical reduction of the carbyne complex (1) with acetylacetone. Crystal structure analysis shows the acetylene C atoms to be symmetrically bonded to the W atom.