Complex‐Stabilized Hydroxy ( p ‐tolyl)acetylene by Reaction of  trans ‐Chlorotetracarbonyl(tolylcarbyne)tungsten with Acetylacetone | Zendy

Fischer Ernst Otto | Zendy; Friedrich Peter | Zendy

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Complex‐Stabilized Hydroxy ( p ‐tolyl)acetylene by Reaction of trans ‐Chlorotetracarbonyl(tolylcarbyne)tungsten with Acetylacetone

Author(s) -

Fischer Ernst Otto,

Friedrich Peter

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197903271

Subject(s) - acetylacetone , acetylene , carbyne , chemistry , tungsten , crystal structure , atom (system on chip) , photochemistry , transition metal , crystallography , carbene , catalysis , inorganic chemistry , organic chemistry , computer science , embedded system

An “acetylene alcohol” , which is stabilized by coordination to a transition metal to atom, arises on photochemical reduction of the carbyne complex (1) with acetylacetone. Crystal structure analysis shows the acetylene C atoms to be symmetrically bonded to the W atom.

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