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Novel Titanium Halides Containing Metal‐Metal Bonds: Ti 7 Cl 16 and Ti 7 Br 16
Author(s) -
Schäfer Harald,
Laumanns Reinhard,
Krebs Bernt,
Henkel Gerald
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197903251
Subject(s) - halide , titanium , metal , chemical bond , materials science , metal halides , inorganic chemistry , group 2 organometallic chemistry , crystallography , chemistry , molecule , metallurgy , organic chemistry
The discovery of two new titanium halides came as a surprise. The isotypic compounds Ti 7 Cl 16 and Ti 7 Br 16 are produced by chemical transport ( via gaseous complexes); X‐ray analysis shows them to contain TiTi bonds.