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Directed Synthesis of Acyl Ortho Esters
Author(s) -
Wulff Günter,
Schröder Ulrich,
Schmidt Wolfram
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197903091
Subject(s) - chemistry , acylation , glycoside , acyl group , stereochemistry , group (periodic table) , combinatorial chemistry , organic chemistry , catalysis
Acyl ortho esters such as (1) —postulated as intermediates in neighboring group reactions—have now been produced by a directed synthesis. These highly reactive compound could be of use in the production of 1,2‐ trans ‐glycosides.