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Cyclodiaza‐λ 6 ‐thianes—Syntheses and Structures
Author(s) -
Tesky FrankMichael,
Mews Rüdiger,
Kerbs Bernt
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197902351
Subject(s) - ring (chemistry) , planar , stereochemistry , chemistry , mathematics , computer science , organic chemistry , computer graphics (images)
The shape of the (SN) 2 ring is highly dependent upon the ligands: the ring is nonplanar in (1) but planar in (2) . Compound (1) is obtained from (Me 3 CN) 3 S and C 2 F 5 NCO, and (2) from (Me 3 SiN) 3 S and i ‐C 3 F 7 NSO.