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Stable Coordination Compounds of “Thiazyl Fluoride”: Structure of [Co(NSF) 6 ] 2+ in the Crystal
Author(s) -
Buss Bruno,
Jones Peter G.,
Mews Rüdiger,
Noltemeyer Mathias,
Sheldrick George M.
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197902311
Subject(s) - fluoride , fluorine , chemistry , crystal structure , sulfur , crystallography , inorganic chemistry , molecule , organic chemistry
“Thiazyl fluoride” (NSF) , the simplest nitrogen‐sulfur‐fluorine compound, is unstable at room temperature. It has now been stabilized as [Co(NSF) 6 ][AsF 6 ] 2 . The pronounced shortening of the SF and the SN bonds on complexation is worthy of note.