Intermolecular Exchange of Substituents  via  lons (Ion Pairs) in Cyclopentadienyl‐ and Cyclononatetraenyl‐trimethylstannane | Zendy

Boche Gernot | Zendy; Heidenhain Frank | Zendy; Staudigl Brigitte | Zendy

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Intermolecular Exchange of Substituents via lons (Ion Pairs) in Cyclopentadienyl‐ and Cyclononatetraenyl‐trimethylstannane

Author(s) -

Boche Gernot,

Heidenhain Frank,

Staudigl Brigitte

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197902181

Subject(s) - intermolecular force , intramolecular force , cyclopentadienyl complex , solvation , chemistry , derivative (finance) , ion , solvent , computational chemistry , intermolecular interaction , crystallography , stereochemistry , molecule , organic chemistry , catalysis , financial economics , economics

Formation of ion pair by solvation is invoked to explain the 1 H‐NMR spectral result obtained for (1) and the analogous cyclonatetraene derivative. Thus (1) is capable of not only intramolecular exchange [ (1′) ⇄ (1) ] but also intermolecular exchange of substituents ( e.g in HMPT as doner solventDo).

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