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Flash Vacuum Thermolysis of Doubly Unsaturated Acyl Halides to Give Phenols
Author(s) -
Dehmlow Eckehard V.,
Slopianka Marion
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197901701
Subject(s) - thermal decomposition , torr , phenol , flash (photography) , phenols , chemistry , halide , chloride , decomposition , flash vacuum pyrolysis , organic chemistry , medicinal chemistry , photochemistry , pyrolysis , physics , thermodynamics , optics
The simplest dienylketene‐phenol rearrangement has been achieved by vacuum flash thermolysis of sorboyl chloride at 6 × 10 −5 torr/660°C. Other dienylketenes can also be generated under these conditions.