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S 2 2− as Simultaneous End‐on and Side‐on Bonded Ligand in the Novel Transition‐Metal Complex [Mo 4 (NO) 4 S 13 ] 4−
Author(s) -
Müller Achim,
Eltzner Werner,
Mohan Nageswaran
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197901681
Subject(s) - transition metal , sulfur , ligand (biochemistry) , crystallography , chemistry , metal , stereochemistry , organic chemistry , biochemistry , receptor , catalysis
Five different bonding states of sulfur are found in complex (1). It is a further example of the importance of S 2 2−ligands in the stabilization of unusual coordination compounds of transition metals.