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Stepwise Addition of a Lewis Acid and a Lewis Base to a Metal‐Metal Bond
Author(s) -
Werner Helmut,
Hofmann Werner
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197901581
Subject(s) - lewis acids and bases , chemistry , metal , bond cleavage , cleavage (geology) , polymer chemistry , stereochemistry , catalysis , organic chemistry , materials science , fracture (geology) , composite material
Cleavage of the CoCo bond in the complex is feasible without disrupting the binuclear structure. Thus a Lewis acid, e.g. CF 3 COOH, and a Lewis base. e.g. PMe 3 , can be added successively to (1) .