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An Example of the Equilibrium Ethylenehydridometal ⇌ Ethylmetal Complex
Author(s) -
Werner Helmut,
Feser Rainer
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197901571
Subject(s) - metal , chemistry , thermodynamics , physics , organic chemistry
An understanding of the processes involved in the insertion of olefins into MH bonds is important for many catalytic processes. Equilibrium between an ethylenehydrido‐metal (1) and an ethyl‐metal complex (2) in solution has been demonstrated for the first time.